Preface to seventh edition .
From preface to the first edition
From preface to the fifth edition
From preface to the sixth edition
Chapter 1 Introduction
Chapter 2 Experimental techniques
2.1 Introduction
2.2 Dry tests
2.3 Wet reactions; macro apparatus and analytical operations on a macro scale
2.4 Semimicro apparatus and semimicro analytical operations
2.5 Micro apparatus and microanalytical operations
2.6 Spot test analysis
2.7 Detect[on of metals by flame atomic spectrometric methods
Chapter 3 Reactions of the cations
3.1 Classification of cations (metal ions) in ahalytical groups
3.2 Notes on the study of the reactions of ions
3.3 First group of cations: lead(II), mercury(I), and silver(I)
3.4 Lead, Pb (Ar: 207.19)
3.5 Mercury, Hg (Ar: 200.59) - mercury(I)
3.6 Silver, Ag (Ar: 107.868)
3.7 Second group of cations: mercury(II), lead(II), bismuth(III), copper(II), cadmium(II), arsenic(III) and (V), antimony(III) and (V), and tin(II) and (IV)
3.8 Mercury, Hg (Ar: 200.59) - mercury(II)
3.9 Bismuth, Bi (Ar: 208.98)
3.10 Copper, Cu (Ar: 63.55)
3.11 Cadmium, Cd (Ar: 112.40)
3.12 Arsenic, As (Ar: 74.92) -- arsenic(III)
3.13 Arsenic, As (Ar: 74.92)- arsenic(V)
3.14 Special tests for small amounts of arsenic
3.15 Antimony, Sb (Ar: 121.75) - antimony(III)
3.16 Antimony, Sb (Ar: 121.75) - antimony(V)
3.17 Special tests for small amounts of antimony
3.18 Tin, Sn (Ar: 118.69) - tin(II)
3.19 Tin, Sn (Ar: 118.69) -tin(IV)
3.20 Third group of cations: iron(II) and (III), aluminium(III), chromium(III) and (VI), nickel(II), cobalt(II), manganese(II) and (VII), and zinc(II)
3.21 Iron, Fe (Ar: 55.85) - iron(II)
3.22 Iron, Fe (Ar: 55.85) - iron(III)
3.23 Aluminium, Al (Ar: 26.98)
3.24 Chromium, Cr (Ar: 51.996) - chromium(III)
3.25 Oxoanions of Group III metals: chromate and permanganate
3.26 Cobalt, Co (Ar: 58.93)
3.27 Nickel, Ni (Ar: 58.71)
3.28 Manganese, Mn (Ar: 54.938) - manganese(II)
3.29 Zinc, Zn (Ar: 63.38)
3.30. Fourth group of cations: barium(II), strontium(II), and calcium(II)
3.31 Barium, Ba (Ar: 137.34)
3.32 Strontium, Sr (Ar: 87.62)
3.33 Calcium, Ca (Ar: 40.08)
3.34 Fifth group of cations: magnesium(II), sodium(I), potassium(I) and ammonium(I)
3.35 Magnesium, Mg (Ar: 24.305)
3.36 Potassium, K (Ar: 39.098)
3.37 Sodium, Na (Ar: 22.99)
3.38 Ammonium, NH+4(Mr: 18.038)
Chapter 4 Reactions of the anions
4.1 Scheme of classification
4.2 Carbonates, CO32-
4.3 Hydrogen carbonates, HCO3-
4.4 Sulphites, SO23-
4.5 Thiosulphates, S2O23-
4.6 Sulphides, S2
4.7 Nitrites, NO2-
4.8 Cyanides, CN-
4.9 Cyanates, OCN-
4.10 Thiocyanates, SCN-
4.11 Hexacyanoferrate(II) ions, [Fe(CN)6]
4.12 Hexacyanoferrate(III) ions, [Fe(CN)6]3- ..
4.13 Hypochlorites, OCI-
4.14 Chlorides, CI-
4.15 Bromides, Br-
4.16 iodides, I-
4.17 Fluorides, F-
4.18 Nitrates, NO3-
4.19 Chlorates, CIO3-
4.20 Bromates, BrO3-
4.21 Iodates, IO3-
4.22 Perchl0rates, CIO4-
4.23 Borates, BO33-, B4072-, BO2-
4.24 Sulphates, SO42-
4.25 Peroxodisulphates, S2O28-
4.26 Silicates, SiO32-
4.27 Hexafluorosilicates (silicofluorides), [SiFs]2-
4.28 Orthophosphates, PO34-
4.29 Pyrophosphates, P2O47-, and metaphosphates, PO3-
4.30 Phosphites, HPO2-
4.31 Hypophosphites, H2PO2-
4.32 Arsenites, AsO3-, and arsenates, AsO3-
4.33 Chromates, CrO2-, and dichromates, Cr2O72-
4.34 Permanganates, MnO4-
4.35 Acetates, CH3COO-
4.36 Formates, HCOO-
4.37 Oxalates,(COO)2-
4.38 Tartrates, C4H4O2-
4.39 Citrates, C6H5O73-
4.40 Salicylates, C6H4(OH)COO-- or C7H5O3-
4.41 Benzoates, C6H5COO- or C7H5O2-
4.42 Succinates, C4H4O2-
4.43 Hydrogen peroxide, H202 (the perhydroxyl ion, OOH-)
4.44 Dithionites, S2O42-
Chapter 5 Selected tests and separations
5.1 Introduction
5.2 Preliminary tests on liquid samples (samples in solution)
5.3 Preliminary tests on non-metallic solid samples
5.4 Preliminary tests on metal samples
5.5 Dissolution of the sample
5.6 Examination of the insoluble residue
5.7 Testing for a single cation in solution
5.8 Separation and identification of cations in mixtures
5.9 Special tests for mixtures of anions
Chapter 6 Reactions of some less common ions
6.1 Introduction
6.2 Thallium, TI (Ar: 204.34) - thallium(I)
6.3 Thallium, TI (Ar: 204.34) - thallium(III)
6.4 Tungsten, W (Ar: 183.85) - tungstate
6.5 Separation and identification of Group I cations in the presence of thallium and tungsten
6.6 Molybdenum, Mo (Ar: 95.94) - molybdate
6.7 Gold, Au (Ar: 196.97) - gold(III)
6.8 Platinum, Pt (Ar: 195.09)
6.9 Palladium, Pd (Ar: 106.4)
6.10 Selenium, Se (Ar: 78.96) - selenites, SeO2-
6.11 Selenium, Se (Ar: 78.96) - selenates, SeO2-4
6.12 Tellurium, Te (Ar: 127.60) - tellurites, TeO2-3
6.13 Tellurium, Te (Ar: 127.60) - telturates, TeO2-
6.14 Separation and identification of Group II cations in the presence of molybdenum, gold; platinum, palladium, selenium, and tellurium
6.15 Vanadium, V (Ar: 50.94) - vanadate
6.16 Beryllium, Be (Ar: 9.01)
6.17 Titanium, Ti (Ar: 47.90) - titanium(IV)
6.18 Zirconium, Zr (Ar: 91.22)
6.19 Uranium, U (Ar: 238.03)
6.20 Thorium, Th (Ar: 232.04)
6.21 Cerium, Ce (Ar: 140.12) - cerium(III)
6.22 Cerium, Ge (Ar: 140.12) - cerium(IV)
6.23 Separation of Group III cations in the presence of titanium, zirconium, thorium, uranium, cerium, vanadium, thallium, and molybdenum
6.24 Lithium, Li (,Ar: 6.94)
Appendix
Index ...
