陶瓷新型胶态成型工艺(英文版)

本书系统、完整地介绍了清华大学黄勇科研组在过去20多年里在高性能陶瓷成型工艺领域取得的研究成果，同时，还论述了其他国家学者近年来在陶瓷成型领域所取得的进展。本书内容分为7章，包括：基于凝胶体系的陶瓷胶态注射成型新工艺；陶瓷基片的凝胶流延工艺；无毒或低毒体系凝胶成型工艺；陶瓷制备过程中缺陷的产生、演化、遗传和控制：非氧化物陶瓷凝胶注模成型新工艺；胶态成型工艺的应用；胶态成型工艺新方法和新技术。

Chapter 1 Aqueous Colloidal Injection Molding of Ceramics Based on Gelation[BR]1.1 Colloidal Injection Molding[BR]1.1.1 The Concept of CIMC[BR]1.1.2 The Flowchart of CIMC[BR]1.1.3 The Machine of CIMC[BR]1.2 Pressure Induced Forming[BR]1.2.1 Effect of Hydrostatic Pressure on Solidification[BR]1.2.2 Homogeneity of the Green Bodies[BR]1.2.3 Controlling the Inner Stress in the Green Body[BR]1.3 Storage Stability of Ceramic Slurries[BR]1.3.1 The Importance of Storage Stability of Slurry[BR]1.3.2 Chemical Stability[BR]1.3.3 Inhibitor for Slurry Storage[BR]1.4 To Prepare High Reliability Ceramic Parts with Complex Shapes Aqueous Colloidal Injection Molding[BR]References[BR]Chapter 2 Gel-Tape-Casting of Ceramic Substrates[BR]2.1 Fundamental Principle and Processing of Aqueous Gel-Tape-Casting[BR]2.1.1 Tape Casting Types and the Raw Materials[BR]2.1.2 Polymerization of the Monomer[BR]2.1.3 Influence Factors on Polymerization of the Monomer[BR]2.1.4 Processing of the Gel-Tape-Casting[BR]2.2 The Characteristics of Slurries Used for Aqueous Gel-Tape-Casting[BR]2.2.1 The Properties of the Aqueous Ceramic Slurries with Binder[BR]2.2.2 The Influence of Dispersants on Stability and Rheology of Aqueous Ceramic Slurries with Organic Monomer[BR]2.2.3 The Influence of Plasticizer on Properties of Aqueous Ceramic Slurry with Organic Monomer[BR]2.2.4 The Influence of pH on the Properties of Slurries with Organic Monomer[BR]2.2.5 The Effect of Surfactant on Wetting and Green Tape Releasing (Separating)[BR]2.2.6 Foam and Pore Elimination[BR]2.2.7 Sintering of Green Tape Prepared by Slurry[BR]2.3 Aqueous Gel-Tape-Casting with Styrene-Acrylic Latex Binder[BR]2.3.1 The Importance of Binders in Gel-Tape-Casting Process[BR]2.3.2 The Forming Film\' Mechanism of Latex Binder[BR]2.3.3 Rheological Properties of the Alumina Slurries with Binder[BR]2.3.4 The Physical Properties and Microstructure of Green Tapes with Latex Binder[BR]2.4 A Gel-Tape-Casting Process Based on Gelation of Sodium Alginate[BR]2.4.1 Why Study on Tape Casting of Sodium Alginate[BR]2.4.2 The Preparation of Aqueous Alumina Suspensions with Sodium Alginate and Calcium Phosphere Tribasic[BR]2.4.3 Control of the Gelation of Sodium Alginate[BR]2.4.4 Characterization of Green Tapes[BR]2.5 The Spray Trigger Fast-Curing for the Gel-Tape-Casting Process[BR]2.5.1 The Idea of the Spray Trigger Fast-Curing[BR]2.5.2 Outline of the New Process[BR]2.6 The Features and Prospects of the Aqueous Tape-Casting[BR]References[BR]Chapter 3 Gelation Forming Process for Low Toxicity System[BR]3.1 Gelation Forming of Ceramic Suspension with Agarose[BR]3.1.1 Characteristics of Agarose[BR]3.1.2 The Effect of Agarose Contents on the R_heology of Aqueous Ceramic Suspensions[BR]3.1.3 The Forming Courses of the Aqueous Ceramic Suspensions with Agarose[BR]3.2 Alumina Casting Based on Gelation of Gelatine[BR]3.2.1 Characteristics of Gelatine[BR]3.2.2 The Gelation Process of the Ceramic Slurry with Gelatine Solution[BR]3.2.3 The Preparation of Green Body Using Slurry with Gelatine Solution[BR]3.3 A Casting Forming for Ceramics by Gelatine and Enzyme Catalysis[BR]3.3.1 Research Background[BR]3.3.2 The Gelation Mechanism of Gelatine Solution with Urea under Enzyme Catalysis[BR]3.3.3 The Rheology and Zeta Potential of Alumina Suspension Containing Gelatine and Urea[BR]3.3.4 The Coagulation Forming and Microstructure of Green Body[BR]3.4 The Alumina Forming Based on Gelation of Sodium Alginate[BR]3.4.1 Research Background[BR]3.4.2 The Gelation Principle of Sodium Alginate[BR]3.4.3 The Preparation Process of Alumina Green Bodies and Samples by Sodium Alginate[BR]3.5 The Gel-Casting of SiC Based on Gelation of Sodium Alginate[BR]3.5.1 Introduction of the Research[BR]3.5.2 The Effect of Dispersant on the Colloidal Behaviors of the SiC Suspension[BR]3.5.3 The Rheological Property of SiC Suspension[BR]3.5.4 The Sedimentation Behavior of the SiC Suspension[BR]3.5.5 The Gelation Principle and Process of the Alginate Solution[BR]3.5.6 The Gelation of the SiC Suspension with Alginate[BR]3.6 The Alumina Gel-Casting with a Low-Toxicity System of HEMA[BR]3.6.1 The Academic Idea and Research Program[BR]3.6.2 The Colloidal Chemistry and Rheological Property[BR]3.6.3 The Binder Burnout and Application of the New System[BR]3.7 The Synergistic Low-Toxicity Gel-Casting System by Using HEMA and PVP[BR]3.7.1 The Academic Idea and Research Program[BR]3.7.2 Zeta Potentials and Rheological Properties[BR]3.7.3 The Activation Energy and Solidification[BR]3.7.4 The Green Strengths and Microstructures[BR]3.7.5 The Exfoliation Elimination Effect and Analysis of the Interaction between PVP and HEMA Molecules[BR]References[BR]Chapter 4 Generation, Development, Inheritance, and Control of the Defects during the Transformation from Suspension to Green Body[BR]4.1 The Rheological Behaviors of Aqueous Ceramic Suspensions[BR]4.1.1 The Rheological Behaviors of Aqueous Alumina Suspensions[BR]4.1.2 The Effect of Rheological Properties of Suspension on Mechanical Strength of Ceramics[BR]4.1.3 The Effect of Solid Loading on Colloidal Forming[BR]4.2 The Generation and Development of Defects[BR]4.2.1 The Generation Mechanisms of Agglomerations in Ceramic Suspensions[BR]4.2.2 The Influences of Idle Time on Microstructures and Mechanical Properties of Green Bodies by Direct Coagulation Casting[BR]4.3 The Effect of Ionic Conductance on Preparation of Highly Concentrated Suspension[BR]4.3.1 The Academic Idea and Research Program[BR]4.3.2 The Relationship Between Ion Conductivity Constants and Solid Loading[BR]4.4 Control of Inner Stress in Green Body[BR]4.4.1 Origin, Transformation and Control of Inner Stress in Green Body[BR]4.4.2 The Release and Control of Inner Stresses in Ceramic Green Body[BR]4.5 The Suppression of Surface-Exfoliation with the Addition of Organic Agents[BR]4.5.1 The Suppression of Surface-Exfoliation by Introducing PAM into Monomer System in Suspension[BR]4.5.2 The Suppression of Surface-Exfoliation by Introducing Polyethylene Glycol into Monomer System in Suspension[BR]4.5.3 The Suppression of Surface-Exfoliation by Introducing Poly-vinylpyrrolidone (PVP) into Monomer System in Suspension[BR]References[BR]Chapter 5 The Gel-Casting of Non-Oxide Ceramics[BR]5.1 The Effects of Powder Surface Modification on Concentrated Suspensions Properties of Si3N4[BR]5.1.1 The Contributing Factor and Elimination of Macropores in Si3N4 Green Bodies[BR]5.1.2 The Effect of Foreign Ions on Concentrated Suspension of Si3N4[BR]5.1.3 The Effect of Acid Cleaning and Calcinations on the Suspension Properties of Si3N4[BR]5.1.4 The Effect of Liquid Medium and Surface Group on Dispersibility of Si3N4 Powder[BR]5.2 The Gel-Casting of Si3N4 Ceramics[BR]5.2.1 The Preparation of Si3N4 Ceramics with Surface-Coated Si3N4 Powder[BR]5.2.2 The Preparation of Si3N4 Ceramics with Surface-Oxidized Si3N4 Powder[BR]5.2.3 The Preparation of Si3N4 Ceramics with Combination Processing[BR]5.3 The Gel-Casting of SiC Ceramic and Si3N4 Bonded SiC Ceramic,[BR]5.3.1 The Gel-Casting of Concentrated Aqueous SiC Ceramic[BR]5.3.2 The Gel-Casting of Aqueous Slurry with Si3N4 Bonded SiC[BR]References[BR]Chapter 6 Application of New Colloidal Forming[BR]6.1 Ceramic Microbeads[BR]6.1.1 The Forming Principle of Ceramic Microbeads Based on Gel-Casting[BR]6.1.2 The Processing of Microbeads[BR]6.1.3 The Properties of Ceramic Microbeads[BR]6.2 Improving the Breakdown Strength of Rutile Capacitor[BR]6.2.1 The Influence of Sintering Additives on the Flow Behavior ..[BR]6.2.2 The Calcining of the Rutile Mixture[BR]6.2.3 The Rheological Behavior of the Calcined Rutile Mixture[BR]6.2.4 The Gel-Casting of the Calcined Rutile Mixture[BR]6.3 The Thin-Wall Rutile Tube for Ozone Generator with High Dielectric Constant[BR]6.3.1 The Experiment Results[BR]6.4 The Refractory Nozzle of Zirconia[BR]6.4.1 The Rehological Behaviors of ZrO2 Suspensions with Different Dispersants[BR]6.4.2 The Sediment Stability of ZrO2 Suspension with Different Dispersants[BR]6.4.3 The Preparation of ZrO2 Refractory Nozzles[BR]6.5 Water Based Gel-Casting of PZT[BR]6.5.1 The Colloidal Chemistry and Rheological Behavior[BR]6.5.2 The Microstructure and Properties[BR]References[BR]Chapter 7 The New Methods and Techniques Based on Gel-Casting[BR]7.1 Development Overview and Application of SFF[BR]7.1.1 Development Overview of SFF[BR]7.1.2 Application of SFF[BR]7.2 Development Overview and Application of Freeze-Gel-Casting[BR]7.2.1 The Combination of Gel-Casting and Freeze-Casting Technique[BR]7.2.2 Fabrication of Ceramics with Special Porous Structures[BR]7.2.3 The Microstructure and Properties of Porous Alumina Ceramics[BR]7.2.4 The Mechanical Properties and Applications of Alumina Ceramics with Ultra Low Density[BR]7.3 The Solidification of Concentrated Si3N4 Suspensions for[BR]Gelcasting by Ultrasonic Effects[BR]7.3.1 Gelcasting by Ultrasonic Effects[BR]7.3.2 The Preparation of Concentrated Si3N4 Suspensions[BR]7.3.3 The Ultrasonic Accelerated Solidification[BR]7.3.4 The Comparison between Thermal and Ultrasonic Activated Solidifications[BR]7.4 Novel Laser Machining Technology for Al2O3 Green Ceramic[BR]7.4.1 Laser Machining Technology[BR]7.4.2 Practical Application of Laser Machining Technology[BR]References[BR]Appendix 1 The Testing and Analyzing Methods Used in Authors\' Research[BR]Appendix 2 The Raw Materials Used in Authors\' Research[BR]Index of Terms[BR]Index of Scholars[BR]Postscript